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H-Bonded Counterion-Directed Enantioselective Au(I) Catalysis

[Image: see text] A new strategy for enantioselective transition-metal catalysis is presented, wherein a H-bond donor placed on the ligand of a cationic complex allows precise positioning of the chiral counteranion responsible for asymmetric induction. The successful implementation of this paradigm...

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Detalles Bibliográficos
Autores principales: Franchino, Allegra, Martí, Àlex, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895408/
https://www.ncbi.nlm.nih.gov/pubmed/35138843
http://dx.doi.org/10.1021/jacs.1c11978