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Small symmetry-breaking triggering large chiroptical responses of Ag(70) nanoclusters
The origins of the chiroptical activities of inorganic nanostructures have perplexed scientists, and deracemization of high-nuclearity metal nanoclusters (NCs) remains challenging. Here, we report a single-crystal structure of Rac-Ag(70) that contains enantiomeric pairs of 70-nuclearity silver clust...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8897454/ https://www.ncbi.nlm.nih.gov/pubmed/35246541 http://dx.doi.org/10.1038/s41467-022-28893-6 |