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Disclosing the Role of C4-Oxo Substitution in the Photochemistry of DNA and RNA Pyrimidine Monomers: Formation of Photoproducts from the Vibrationally Excited Ground State
[Image: see text] Oxo and amino substituted purines and pyrimidines have been suggested as protonucleobases participating in ancient pre-RNA forms. Considering electromagnetic radiation as a key environmental selection pressure on early Earth, the investigation of the photophysics of modified nucleo...
Autores principales: | Vos, Eva, Hoehn, Sean J., Krul, Sarah E., Crespo-Hernández, Carlos E., González-Vázquez, Jesús, Corral, Inés |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900130/ https://www.ncbi.nlm.nih.gov/pubmed/35191712 http://dx.doi.org/10.1021/acs.jpclett.2c00052 |
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