Crystal structure of (7-{[bis­(pyridin-2-ylmeth­yl)amino-κ(3) N,N′,N′′]meth­yl}-5-chloro­quinolin-8-ol)di­bromidozinc(II)

In the title compound, [ZnBr(2)(C(22)H(19)ClN(4)O)], the Zn(II) atom adopts a distorted square-pyramidal coordination geometry, formed by two bromido ligands and three N atoms of the bis­(pyridin-2-ylmeth­yl)amine moiety in the penta­dentate ligand containing quinolinol. The Zn(II) atom is located well above the mean basal plane of the square-based pyramid. The apical position is occupied by a Br atom. The O and N atoms of the quinolinol moiety in the ligand are not coordinated to the Zn(II) atom. An intra­molecular O—H⋯N hydrogen bond, generating an S(5) ring motif, stabilizes the mol­ecular structure. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯Br hydrogen bonds, generating ribbon structures containing alternating R (2) (2)(22) and R (2) (2)(14) rings. These ribbons are linked through an inter­molecular C—H⋯Br hydrogen bond, forming a two-dimensional network sheet.