Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene

The title compound, (3)Cp(2)Mg or [Mg(C(14)H(23))(2)], was synthesized from the cor­res­ponding triiso­propyl­cyclo­penta­diene by treatment with n-butyl-sec-butyl­magnesium. The structural characterization by single-crystal X-ray diffraction revealed that the compound crystallizes in the triclinic...

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Autores principales: Bachmann, Nico, Wirtz, Lisa, Morgenstern, Bernd, Müller, Carsten, Schäfer, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900506/
https://www.ncbi.nlm.nih.gov/pubmed/35371551
http://dx.doi.org/10.1107/S2056989022001189
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author Bachmann, Nico
Wirtz, Lisa
Morgenstern, Bernd
Müller, Carsten
Schäfer, André
author_facet Bachmann, Nico
Wirtz, Lisa
Morgenstern, Bernd
Müller, Carsten
Schäfer, André
author_sort Bachmann, Nico
collection PubMed
description The title compound, (3)Cp(2)Mg or [Mg(C(14)H(23))(2)], was synthesized from the cor­res­ponding triiso­propyl­cyclo­penta­diene by treatment with n-butyl-sec-butyl­magnesium. The structural characterization by single-crystal X-ray diffraction revealed that the compound crystallizes in the triclinic space group P [Image: see text] with half a mol­ecule per asymmetric unit and a staggered arrangement of the cyclo­penta­dienide ligands.
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spelling pubmed-89005062022-03-31 Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene Bachmann, Nico Wirtz, Lisa Morgenstern, Bernd Müller, Carsten Schäfer, André Acta Crystallogr E Crystallogr Commun Research Communications The title compound, (3)Cp(2)Mg or [Mg(C(14)H(23))(2)], was synthesized from the cor­res­ponding triiso­propyl­cyclo­penta­diene by treatment with n-butyl-sec-butyl­magnesium. The structural characterization by single-crystal X-ray diffraction revealed that the compound crystallizes in the triclinic space group P [Image: see text] with half a mol­ecule per asymmetric unit and a staggered arrangement of the cyclo­penta­dienide ligands. International Union of Crystallography 2022-02-03 /pmc/articles/PMC8900506/ /pubmed/35371551 http://dx.doi.org/10.1107/S2056989022001189 Text en © Bachmann et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bachmann, Nico
Wirtz, Lisa
Morgenstern, Bernd
Müller, Carsten
Schäfer, André
Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title_full Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title_fullStr Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title_full_unstemmed Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title_short Crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
title_sort crystal structure of 1,1′,2,2′,4,4′-hexa­iso­propyl­magnesocene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900506/
https://www.ncbi.nlm.nih.gov/pubmed/35371551
http://dx.doi.org/10.1107/S2056989022001189
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AT morgensternbernd crystalstructureof112244hexaisopropylmagnesocene
AT mullercarsten crystalstructureof112244hexaisopropylmagnesocene
AT schaferandre crystalstructureof112244hexaisopropylmagnesocene

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