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In situ beam reduction of Pu(IV) and Bk(IV) as a route to trivalent transuranic coordination complexes with hydroxypyridinone chelators

The solution-state interactions of plutonium and berkelium with the octadentate chelator 3,4,3-LI(1,2-HOPO) (343-HOPO) were investigated and characterized by X-ray absorption spectroscopy, which revealed in situ reductive decomposition of the tetravalent species of both actinide metals to yield Pu(I...

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Detalles Bibliográficos
Autores principales:	Carter, Korey P., Wacker, Jennifer N., Smith, Kurt F., Deblonde, Gauthier J.-P., Moreau, Liane M., Rees, Julian A., Booth, Corwin H., Abergel, Rebecca J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2022
Materias:	Actinide Physics and Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900832/ https://www.ncbi.nlm.nih.gov/pubmed/35254293 http://dx.doi.org/10.1107/S1600577522000200

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