Deconjugative α-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids

[Image: see text] A general and efficient method for the deconjugative α-alkylation of α,β-unsaturated aldehydes promoted by a synergistic effect between (t)BuOK and NaH, which considerably increases the reaction rate under mild conditions, is reported. The β,γ-unsaturated aldehyde, resulting from t...

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Detalles Bibliográficos
Autores principales: Chahboun, Rachid, Botubol-Ares, José Manuel, Durán-Peña, María Jesús, Jiménez, Fermín, Alvarez-Manzaneda, Ramón, Alvarez-Manzaneda, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8901105/
https://www.ncbi.nlm.nih.gov/pubmed/34128666
http://dx.doi.org/10.1021/acs.joc.1c00560

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8901105/
https://www.ncbi.nlm.nih.gov/pubmed/34128666
http://dx.doi.org/10.1021/acs.joc.1c00560

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