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High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode

[Image: see text] Energy issues have attracted great concern worldwide. Developing new energy has been the main choice, and the exploitation of the electrochemical energy storage devices plays an important role. Herein, a high-performance dual-ion battery system is proposed, which consists of a grap...

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Detalles Bibliográficos
Autores principales: Fang, Yao-Bing, Zheng, Wen, Hu, Tao, Li, Li, Yuan, Wen-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8908483/
https://www.ncbi.nlm.nih.gov/pubmed/35284716
http://dx.doi.org/10.1021/acsomega.1c06134
Descripción
Sumario:[Image: see text] Energy issues have attracted great concern worldwide. Developing new energy has been the main choice, and the exploitation of the electrochemical energy storage devices plays an important role. Herein, a high-performance dual-ion battery system is proposed, which consists of a graphite cathode and SnS(2) anode, with a high-concentration lithium salt electrolyte (4 M LiTFSI). The benefits from the typical sandwich-like layer structure of SnS(2) are as follows: the highest discharge specific capacity of the battery could reach 130.0 mA h g(–1) at a current density of 100 mA g(–1), and even under an ultra-high current density of 2000 mA g(–1), the highest capacity of 66.3 mA h g(–1) is still achieved, with an outstanding capacity retention over 100% after 1000 cycles. Inspiringly, this system delivers an excellent low self-discharge of 1.19%/h, surpassing most of the reported dual-ion batteries. In addition, the working mechanism and structural stability are also investigated by X-ray diffraction and Raman spectra, indicating a good reversibility. These results reveal that this graphite/SnS(2) dual-ion battery system could provide a promising alternative for a future high-performance energy storage device.