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High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode

[Image: see text] Energy issues have attracted great concern worldwide. Developing new energy has been the main choice, and the exploitation of the electrochemical energy storage devices plays an important role. Herein, a high-performance dual-ion battery system is proposed, which consists of a grap...

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Autores principales: Fang, Yao-Bing, Zheng, Wen, Hu, Tao, Li, Li, Yuan, Wen-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8908483/
https://www.ncbi.nlm.nih.gov/pubmed/35284716
http://dx.doi.org/10.1021/acsomega.1c06134
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author Fang, Yao-Bing
Zheng, Wen
Hu, Tao
Li, Li
Yuan, Wen-Hui
author_facet Fang, Yao-Bing
Zheng, Wen
Hu, Tao
Li, Li
Yuan, Wen-Hui
author_sort Fang, Yao-Bing
collection PubMed
description [Image: see text] Energy issues have attracted great concern worldwide. Developing new energy has been the main choice, and the exploitation of the electrochemical energy storage devices plays an important role. Herein, a high-performance dual-ion battery system is proposed, which consists of a graphite cathode and SnS(2) anode, with a high-concentration lithium salt electrolyte (4 M LiTFSI). The benefits from the typical sandwich-like layer structure of SnS(2) are as follows: the highest discharge specific capacity of the battery could reach 130.0 mA h g(–1) at a current density of 100 mA g(–1), and even under an ultra-high current density of 2000 mA g(–1), the highest capacity of 66.3 mA h g(–1) is still achieved, with an outstanding capacity retention over 100% after 1000 cycles. Inspiringly, this system delivers an excellent low self-discharge of 1.19%/h, surpassing most of the reported dual-ion batteries. In addition, the working mechanism and structural stability are also investigated by X-ray diffraction and Raman spectra, indicating a good reversibility. These results reveal that this graphite/SnS(2) dual-ion battery system could provide a promising alternative for a future high-performance energy storage device.
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spelling pubmed-89084832022-03-11 High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode Fang, Yao-Bing Zheng, Wen Hu, Tao Li, Li Yuan, Wen-Hui ACS Omega [Image: see text] Energy issues have attracted great concern worldwide. Developing new energy has been the main choice, and the exploitation of the electrochemical energy storage devices plays an important role. Herein, a high-performance dual-ion battery system is proposed, which consists of a graphite cathode and SnS(2) anode, with a high-concentration lithium salt electrolyte (4 M LiTFSI). The benefits from the typical sandwich-like layer structure of SnS(2) are as follows: the highest discharge specific capacity of the battery could reach 130.0 mA h g(–1) at a current density of 100 mA g(–1), and even under an ultra-high current density of 2000 mA g(–1), the highest capacity of 66.3 mA h g(–1) is still achieved, with an outstanding capacity retention over 100% after 1000 cycles. Inspiringly, this system delivers an excellent low self-discharge of 1.19%/h, surpassing most of the reported dual-ion batteries. In addition, the working mechanism and structural stability are also investigated by X-ray diffraction and Raman spectra, indicating a good reversibility. These results reveal that this graphite/SnS(2) dual-ion battery system could provide a promising alternative for a future high-performance energy storage device. American Chemical Society 2022-02-26 /pmc/articles/PMC8908483/ /pubmed/35284716 http://dx.doi.org/10.1021/acsomega.1c06134 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Fang, Yao-Bing
Zheng, Wen
Hu, Tao
Li, Li
Yuan, Wen-Hui
High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title_full High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title_fullStr High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title_full_unstemmed High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title_short High-Performance Dual-Ion Battery Based on a Layered Tin Disulfide Anode
title_sort high-performance dual-ion battery based on a layered tin disulfide anode
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8908483/
https://www.ncbi.nlm.nih.gov/pubmed/35284716
http://dx.doi.org/10.1021/acsomega.1c06134
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