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Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond
Several sterically protected, low-coordinate organophosphorus compounds with P=P, P=C, and C≡P bond are described in this study. Molecules such as diphosphenes, phosphaalkenes, 1-phosphaallenes, 1,3-diphosphaallenes, 3,4-diphosphinidenecyclobutenes, and phosphaalkynes are stabilized with an extremel...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911619/ https://www.ncbi.nlm.nih.gov/pubmed/35268657 http://dx.doi.org/10.3390/molecules27051557 |
| _version_ | 1784666863310995456 |
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| author | Yoshifuji, Masaaki |
| author_facet | Yoshifuji, Masaaki |
| author_sort | Yoshifuji, Masaaki |
| collection | PubMed |
| description | Several sterically protected, low-coordinate organophosphorus compounds with P=P, P=C, and C≡P bond are described in this study. Molecules such as diphosphenes, phosphaalkenes, 1-phosphaallenes, 1,3-diphosphaallenes, 3,4-diphosphinidenecyclobutenes, and phosphaalkynes are stabilized with an extremely bulky 2,4,6-tri-t-butylphenyl (Mes*) group. The synthesis, structures, physical, and chemical properties of these molecules are discussed, together with some successful applications in catalytic organic reactions. |
| format | Online Article Text |
| id | pubmed-8911619 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-89116192022-03-11 Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond Yoshifuji, Masaaki Molecules Review Several sterically protected, low-coordinate organophosphorus compounds with P=P, P=C, and C≡P bond are described in this study. Molecules such as diphosphenes, phosphaalkenes, 1-phosphaallenes, 1,3-diphosphaallenes, 3,4-diphosphinidenecyclobutenes, and phosphaalkynes are stabilized with an extremely bulky 2,4,6-tri-t-butylphenyl (Mes*) group. The synthesis, structures, physical, and chemical properties of these molecules are discussed, together with some successful applications in catalytic organic reactions. MDPI 2022-02-25 /pmc/articles/PMC8911619/ /pubmed/35268657 http://dx.doi.org/10.3390/molecules27051557 Text en © 2022 by the author. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Review Yoshifuji, Masaaki Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title | Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title_full | Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title_fullStr | Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title_full_unstemmed | Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title_short | Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond |
| title_sort | chemistry of several sterically bulky molecules with p=p, p=c, and c≡p bond |
| topic | Review |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911619/ https://www.ncbi.nlm.nih.gov/pubmed/35268657 http://dx.doi.org/10.3390/molecules27051557 |
| work_keys_str_mv | AT yoshifujimasaaki chemistryofseveralstericallybulkymoleculeswithpppcandcpbond |