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Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water

Extensive use of pesticides resulting in their accumulation in the environment presents a hazard for their non-target species, including humans. Hence, efficient remediation strategies are needed, and, in this sense, adsorption is seen as the most straightforward approach. We have studied activated...

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Autores principales: Jocić, Ana, Breitenbach, Stefan, Bajuk-Bogdanović, Danica, Pašti, Igor A., Unterweger, Christoph, Fürst, Christian, Lazarević-Pašti, Tamara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911764/
https://www.ncbi.nlm.nih.gov/pubmed/35268578
http://dx.doi.org/10.3390/molecules27051477
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author Jocić, Ana
Breitenbach, Stefan
Bajuk-Bogdanović, Danica
Pašti, Igor A.
Unterweger, Christoph
Fürst, Christian
Lazarević-Pašti, Tamara
author_facet Jocić, Ana
Breitenbach, Stefan
Bajuk-Bogdanović, Danica
Pašti, Igor A.
Unterweger, Christoph
Fürst, Christian
Lazarević-Pašti, Tamara
author_sort Jocić, Ana
collection PubMed
description Extensive use of pesticides resulting in their accumulation in the environment presents a hazard for their non-target species, including humans. Hence, efficient remediation strategies are needed, and, in this sense, adsorption is seen as the most straightforward approach. We have studied activated carbon fibers (ACFs) derived from viscose fibers impregnated with diammonium hydrogen phosphate (DAHP). By changing the amount of DAHP in the impregnation step, the chemical composition and textural properties of ACFs are effectively tuned, affecting their performance for dimethoate removal from water. The prepared ACFs effectively reduced the toxicity of treated water samples, both deionized water solutions and spiked tap water samples, under batch conditions and in dynamic filtration experiments. Using the results of physicochemical characterization and dimethoate adsorption measurements, multiple linear regression models were made to reliably predict performance towards dimethoate removal from water. These models can be used to quickly screen among larger sets of possible adsorbents and guide the development of novel, highly efficient adsorbents for dimethoate removal from water.
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spelling pubmed-89117642022-03-11 Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water Jocić, Ana Breitenbach, Stefan Bajuk-Bogdanović, Danica Pašti, Igor A. Unterweger, Christoph Fürst, Christian Lazarević-Pašti, Tamara Molecules Article Extensive use of pesticides resulting in their accumulation in the environment presents a hazard for their non-target species, including humans. Hence, efficient remediation strategies are needed, and, in this sense, adsorption is seen as the most straightforward approach. We have studied activated carbon fibers (ACFs) derived from viscose fibers impregnated with diammonium hydrogen phosphate (DAHP). By changing the amount of DAHP in the impregnation step, the chemical composition and textural properties of ACFs are effectively tuned, affecting their performance for dimethoate removal from water. The prepared ACFs effectively reduced the toxicity of treated water samples, both deionized water solutions and spiked tap water samples, under batch conditions and in dynamic filtration experiments. Using the results of physicochemical characterization and dimethoate adsorption measurements, multiple linear regression models were made to reliably predict performance towards dimethoate removal from water. These models can be used to quickly screen among larger sets of possible adsorbents and guide the development of novel, highly efficient adsorbents for dimethoate removal from water. MDPI 2022-02-22 /pmc/articles/PMC8911764/ /pubmed/35268578 http://dx.doi.org/10.3390/molecules27051477 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Jocić, Ana
Breitenbach, Stefan
Bajuk-Bogdanović, Danica
Pašti, Igor A.
Unterweger, Christoph
Fürst, Christian
Lazarević-Pašti, Tamara
Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title_full Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title_fullStr Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title_full_unstemmed Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title_short Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water
title_sort viscose-derived activated carbons fibers as highly efficient adsorbents for dimethoate removal from water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911764/
https://www.ncbi.nlm.nih.gov/pubmed/35268578
http://dx.doi.org/10.3390/molecules27051477
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