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Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials

Solid state nuclear magnetic resonance (ssNMR) is a powerful and attractive characterization method for obtaining insights into the chemical structure and dynamics of a wide range of materials. Current interest in cellulose-based materials, as sustainable and renewable natural polymer products, requ...

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Autores principales: El Hariri El Nokab, Mustapha, Habib, Mohamed H., Alassmy, Yasser A., Abduljawad, Marwan M., Alshamrani, Khalid M., Sebakhy, Khaled O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8914817/
https://www.ncbi.nlm.nih.gov/pubmed/35267872
http://dx.doi.org/10.3390/polym14051049
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author El Hariri El Nokab, Mustapha
Habib, Mohamed H.
Alassmy, Yasser A.
Abduljawad, Marwan M.
Alshamrani, Khalid M.
Sebakhy, Khaled O.
author_facet El Hariri El Nokab, Mustapha
Habib, Mohamed H.
Alassmy, Yasser A.
Abduljawad, Marwan M.
Alshamrani, Khalid M.
Sebakhy, Khaled O.
author_sort El Hariri El Nokab, Mustapha
collection PubMed
description Solid state nuclear magnetic resonance (ssNMR) is a powerful and attractive characterization method for obtaining insights into the chemical structure and dynamics of a wide range of materials. Current interest in cellulose-based materials, as sustainable and renewable natural polymer products, requires deep investigation and analysis of the chemical structure, molecular packing, end chain motion, functional modification, and solvent–matrix interactions, which strongly dictate the final product properties and tailor their end applications. In comparison to other spectroscopic techniques, on an atomic level, ssNMR is considered more advanced, especially in the structural analysis of cellulose-based materials; however, due to a dearth in the availability of a broad range of pulse sequences, and time consuming experiments, its capabilities are underestimated. This critical review article presents the comprehensive and up-to-date work done using ssNMR, including the most advanced NMR strategies used to overcome and resolve the structural difficulties present in different types of cellulose-based materials.
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spelling pubmed-89148172022-03-12 Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials El Hariri El Nokab, Mustapha Habib, Mohamed H. Alassmy, Yasser A. Abduljawad, Marwan M. Alshamrani, Khalid M. Sebakhy, Khaled O. Polymers (Basel) Review Solid state nuclear magnetic resonance (ssNMR) is a powerful and attractive characterization method for obtaining insights into the chemical structure and dynamics of a wide range of materials. Current interest in cellulose-based materials, as sustainable and renewable natural polymer products, requires deep investigation and analysis of the chemical structure, molecular packing, end chain motion, functional modification, and solvent–matrix interactions, which strongly dictate the final product properties and tailor their end applications. In comparison to other spectroscopic techniques, on an atomic level, ssNMR is considered more advanced, especially in the structural analysis of cellulose-based materials; however, due to a dearth in the availability of a broad range of pulse sequences, and time consuming experiments, its capabilities are underestimated. This critical review article presents the comprehensive and up-to-date work done using ssNMR, including the most advanced NMR strategies used to overcome and resolve the structural difficulties present in different types of cellulose-based materials. MDPI 2022-03-06 /pmc/articles/PMC8914817/ /pubmed/35267872 http://dx.doi.org/10.3390/polym14051049 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
El Hariri El Nokab, Mustapha
Habib, Mohamed H.
Alassmy, Yasser A.
Abduljawad, Marwan M.
Alshamrani, Khalid M.
Sebakhy, Khaled O.
Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title_full Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title_fullStr Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title_full_unstemmed Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title_short Solid State NMR a Powerful Technique for Investigating Sustainable/Renewable Cellulose-Based Materials
title_sort solid state nmr a powerful technique for investigating sustainable/renewable cellulose-based materials
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8914817/
https://www.ncbi.nlm.nih.gov/pubmed/35267872
http://dx.doi.org/10.3390/polym14051049
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