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C–H Insertion via Ruthenium Catalyzed gem-Hydrogenation of 1,3-Enynes

[Image: see text] gem-Hydrogenation of an internal alkyne with the aid of [Cp*RuCl](4) as the precatalyst is a highly unorthodox transformation, in which one C atom of the triple bond is transformed into a methylene group, whereas the second C atom gets converted into a ruthenium carbene. In the cas...

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Detalles Bibliográficos
Autores principales:	Peil, Sebastian, Gutiérrez González, Alejandro, Leutzsch, Markus, Fürstner, Alois
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8915261/ https://www.ncbi.nlm.nih.gov/pubmed/35170941 http://dx.doi.org/10.1021/jacs.1c13446

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