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Al(13)(−) and B@Al(12)(−) superatoms on a molecularly decorated substrate

Aluminum nanoclusters (Al(n) NCs), particularly Al(13)(−) (n = 13), exhibit superatomic behavior with interplay between electron shell closure and geometrical packing in an anionic state. To fabricate superatom (SA) assemblies, substrates decorated with organic molecules can facilitate the optimizat...

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Detalles Bibliográficos
Autores principales: Shibuta, Masahiro, Inoue, Tomoya, Kamoshida, Toshiaki, Eguchi, Toyoaki, Nakajima, Atsushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8921336/
https://www.ncbi.nlm.nih.gov/pubmed/35288553
http://dx.doi.org/10.1038/s41467-022-29034-9