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Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries
Although solid composite electrolytes show tremendous potential for the practical solid‐state lithium metal batteries, searching for a straightforward tactic to promote the ion conduction at electrolyte/electrode interface, especially settling lithium dendrites formation caused by the concentration...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8922129/ https://www.ncbi.nlm.nih.gov/pubmed/35037427 http://dx.doi.org/10.1002/advs.202104506 |
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author | Fan, Rong Liao, Wenchao Fan, Shuangxian Chen, Dazhu Tang, Jiaoning Yang, Yong Liu, Chen |
author_facet | Fan, Rong Liao, Wenchao Fan, Shuangxian Chen, Dazhu Tang, Jiaoning Yang, Yong Liu, Chen |
author_sort | Fan, Rong |
collection | PubMed |
description | Although solid composite electrolytes show tremendous potential for the practical solid‐state lithium metal batteries, searching for a straightforward tactic to promote the ion conduction at electrolyte/electrode interface, especially settling lithium dendrites formation caused by the concentration gradient polarization, are still long‐standing problems. Here, the authors report a corrugated 3D nanowires‐bulk ceramic‐nanowires (NCN) skeleton reinforced composite electrolyte with regulated interfacial Li‐ion transport behavior. The special and integrated NCN skeleton endows the electrolyte with fast Li‐ion transfer and solves the Li(+) concentration polarization at electrode/electrolyte interface, thereby eliminating the energy barrier originated from the redistribution of charge carriers and offering homogeneous interfacial Li‐ion flux on lithium anode. As a “double insurance”, the bulk ceramic sheet in 3D framework enables the electrolyte to block the mobility of anions. The rational designed NCN composite electrolyte exhibits excellent ionic conductivity and the assembled all‐solid‐state battery possesses 90.2% capacity retention after 500 cycles. The proposed strategy affords a special insight in designing high‐performance solid composite electrolytes. |
format | Online Article Text |
id | pubmed-8922129 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-89221292022-03-21 Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries Fan, Rong Liao, Wenchao Fan, Shuangxian Chen, Dazhu Tang, Jiaoning Yang, Yong Liu, Chen Adv Sci (Weinh) Research Articles Although solid composite electrolytes show tremendous potential for the practical solid‐state lithium metal batteries, searching for a straightforward tactic to promote the ion conduction at electrolyte/electrode interface, especially settling lithium dendrites formation caused by the concentration gradient polarization, are still long‐standing problems. Here, the authors report a corrugated 3D nanowires‐bulk ceramic‐nanowires (NCN) skeleton reinforced composite electrolyte with regulated interfacial Li‐ion transport behavior. The special and integrated NCN skeleton endows the electrolyte with fast Li‐ion transfer and solves the Li(+) concentration polarization at electrode/electrolyte interface, thereby eliminating the energy barrier originated from the redistribution of charge carriers and offering homogeneous interfacial Li‐ion flux on lithium anode. As a “double insurance”, the bulk ceramic sheet in 3D framework enables the electrolyte to block the mobility of anions. The rational designed NCN composite electrolyte exhibits excellent ionic conductivity and the assembled all‐solid‐state battery possesses 90.2% capacity retention after 500 cycles. The proposed strategy affords a special insight in designing high‐performance solid composite electrolytes. John Wiley and Sons Inc. 2022-01-17 /pmc/articles/PMC8922129/ /pubmed/35037427 http://dx.doi.org/10.1002/advs.202104506 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Fan, Rong Liao, Wenchao Fan, Shuangxian Chen, Dazhu Tang, Jiaoning Yang, Yong Liu, Chen Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title | Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title_full | Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title_fullStr | Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title_full_unstemmed | Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title_short | Regulating Interfacial Li‐Ion Transport via an Integrated Corrugated 3D Skeleton in Solid Composite Electrolyte for All‐Solid‐State Lithium Metal Batteries |
title_sort | regulating interfacial li‐ion transport via an integrated corrugated 3d skeleton in solid composite electrolyte for all‐solid‐state lithium metal batteries |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8922129/ https://www.ncbi.nlm.nih.gov/pubmed/35037427 http://dx.doi.org/10.1002/advs.202104506 |
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