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Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction
Evolving cost‐effective transition metal phosphides (TMPs) using general approaches for energy storage is pivotal but challenging. Besides, the absence of noble metals and high electrocatalytic activity of TMPs allow their applicability as catalysts in oxygen evolution reaction (OER). Herein, CoNiP‒...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8922135/ https://www.ncbi.nlm.nih.gov/pubmed/35064771 http://dx.doi.org/10.1002/advs.202104877 |
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author | Sekhar, S. Chandra Ramulu, Bhimanaboina Han, Man Ho Arbaz, Shaik Junied Nagaraju, Manchi Oh, Hyung‐Suk Yu, Jae Su |
author_facet | Sekhar, S. Chandra Ramulu, Bhimanaboina Han, Man Ho Arbaz, Shaik Junied Nagaraju, Manchi Oh, Hyung‐Suk Yu, Jae Su |
author_sort | Sekhar, S. Chandra |
collection | PubMed |
description | Evolving cost‐effective transition metal phosphides (TMPs) using general approaches for energy storage is pivotal but challenging. Besides, the absence of noble metals and high electrocatalytic activity of TMPs allow their applicability as catalysts in oxygen evolution reaction (OER). Herein, CoNiP‒CoP(2) (CNP‒CP) composite is in situ deposited on carbon fabric by a one‐step hydrothermal technique. The CNP‒CP reveals hybrid nanoarchitecture (3D‐on‐1D HNA), i.e., cashew fruit‐like nanostructures and nanocones. The CNP‒CP HNA electrode delivers higher areal capacity (82.8 μAh cm(–2)) than the other electrodes. Furthermore, a hybrid cell assembled with CNP‒CP HNA shows maximum energy and power densities of 31 μWh cm(–2) and 10.9 mW cm(–2), respectively. Exclusively, the hybrid cell demonstrates remarkable durability over 30 000 cycles. In situ/operando X‐ray absorption near‐edge structure analysis confirms the reversible changes in valency of Co and Ni elements in CNP‒CP material during real‐time electrochemical reactions. Besides, a quasi‐solid‐state device unveils its practicability by powering electronic components. Meanwhile, the CNP‒CP HNA verifies its higher OER activity than the other catalysts by revealing lower overpotential (230 mV). Also, it exhibits relatively small Tafel slope (38 mV dec(–1)) and stable OER activity over 24 h. This preparation strategy may initiate the design of advanced TMP‐based materials for multifunctional applications. |
format | Online Article Text |
id | pubmed-8922135 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-89221352022-03-21 Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction Sekhar, S. Chandra Ramulu, Bhimanaboina Han, Man Ho Arbaz, Shaik Junied Nagaraju, Manchi Oh, Hyung‐Suk Yu, Jae Su Adv Sci (Weinh) Research Articles Evolving cost‐effective transition metal phosphides (TMPs) using general approaches for energy storage is pivotal but challenging. Besides, the absence of noble metals and high electrocatalytic activity of TMPs allow their applicability as catalysts in oxygen evolution reaction (OER). Herein, CoNiP‒CoP(2) (CNP‒CP) composite is in situ deposited on carbon fabric by a one‐step hydrothermal technique. The CNP‒CP reveals hybrid nanoarchitecture (3D‐on‐1D HNA), i.e., cashew fruit‐like nanostructures and nanocones. The CNP‒CP HNA electrode delivers higher areal capacity (82.8 μAh cm(–2)) than the other electrodes. Furthermore, a hybrid cell assembled with CNP‒CP HNA shows maximum energy and power densities of 31 μWh cm(–2) and 10.9 mW cm(–2), respectively. Exclusively, the hybrid cell demonstrates remarkable durability over 30 000 cycles. In situ/operando X‐ray absorption near‐edge structure analysis confirms the reversible changes in valency of Co and Ni elements in CNP‒CP material during real‐time electrochemical reactions. Besides, a quasi‐solid‐state device unveils its practicability by powering electronic components. Meanwhile, the CNP‒CP HNA verifies its higher OER activity than the other catalysts by revealing lower overpotential (230 mV). Also, it exhibits relatively small Tafel slope (38 mV dec(–1)) and stable OER activity over 24 h. This preparation strategy may initiate the design of advanced TMP‐based materials for multifunctional applications. John Wiley and Sons Inc. 2022-01-22 /pmc/articles/PMC8922135/ /pubmed/35064771 http://dx.doi.org/10.1002/advs.202104877 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Sekhar, S. Chandra Ramulu, Bhimanaboina Han, Man Ho Arbaz, Shaik Junied Nagaraju, Manchi Oh, Hyung‐Suk Yu, Jae Su Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title | Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title_full | Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title_fullStr | Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title_full_unstemmed | Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title_short | Unraveling CoNiP‒CoP(2) 3D‐on‐1D Hybrid Nanoarchitecture for Long‐Lasting Electrochemical Hybrid Cells and Oxygen Evolution Reaction |
title_sort | unraveling conip‒cop(2) 3d‐on‐1d hybrid nanoarchitecture for long‐lasting electrochemical hybrid cells and oxygen evolution reaction |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8922135/ https://www.ncbi.nlm.nih.gov/pubmed/35064771 http://dx.doi.org/10.1002/advs.202104877 |
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