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Covalency in actinide(iv) hexachlorides in relation to the chlorine K-edge X-ray absorption structure

Chlorine K-edge X-ray absorption near edge structure (XANES) in actinide(IV) hexachlorides, [AnCl(6)](2−) (An = Th–Pu), is calculated with relativistic multiconfiguration wavefunction theory (WFT). Of particular focus is a 3-peak feature emerging from U toward Pu, and its assignment in terms of dona...

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Detalles Bibliográficos
Autores principales:	Sergentu, Dumitru-Claudiu, Autschbach, Jochen
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8926251/ https://www.ncbi.nlm.nih.gov/pubmed/35414875 http://dx.doi.org/10.1039/d1sc06454a

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