Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes

Visible light induced singlet nucleophilic carbenes undergo rapid [2 + 1]-cycloaddition with tethered olefins to afford unique bicyclo[3.1.0]hexane and bicyclo[4.1.0]heptane scaffolds. This cyclopropanation process requires only visible light irradiation to proceed, circumventing the use of exogenou...

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Detalles Bibliográficos
Autores principales: Bunyamin, Amanda, Hua, Carol, Polyzos, Anastasios, Priebbenow, Daniel L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8926286/
https://www.ncbi.nlm.nih.gov/pubmed/35414869
http://dx.doi.org/10.1039/d2sc00203e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8926286/
https://www.ncbi.nlm.nih.gov/pubmed/35414869
http://dx.doi.org/10.1039/d2sc00203e

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