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Phosphine-catalyzed divergent domino processes between γ-substituted allenoates and carbonyl-activated alkenes

Highly enantioselective and chemodivergent domino reactions between γ-substituted allenoates and activated alkenes have been developed. In the presence of NUSIOC-Phos, triketone enone substrates smoothly reacted with γ-substituted allenoates to form bicyclic furofurans in good yields with high stere...

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Detalles Bibliográficos
Autores principales: Wu, Mingyue, Han, Zhaobin, Ni, Huanzhen, Wang, Nengzhong, Ding, Kuiling, Lu, Yixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8926293/
https://www.ncbi.nlm.nih.gov/pubmed/35414887
http://dx.doi.org/10.1039/d1sc06364b