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Generation of a μ-1,2-hydroperoxo Fe(III)Fe(III) and a μ-1,2-peroxo Fe(IV)Fe(III) Complex

μ-1,2-Peroxo-diferric intermediates (P) of non-heme diiron enzymes are proposed to convert upon protonation either to high-valent active species or to activated P′ intermediates via hydroperoxo-diferric intermediates. Protonation of synthetic μ-1,2-peroxo model complexes occurred at the μ-oxo and no...

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Detalles Bibliográficos
Autores principales:	Walleck, Stephan, Zimmermann, Thomas Philipp, Hachmeister, Henning, Pilger, Christian, Huser, Thomas, Katz, Sagie, Hildebrandt, Peter, Stammler, Anja, Bögge, Hartmut, Bill, Eckhard, Glaser, Thorsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8927127/ https://www.ncbi.nlm.nih.gov/pubmed/35296656 http://dx.doi.org/10.1038/s41467-022-28894-5

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