Predictive energetic tuning of C-Nucleophiles for the electrochemical capture of carbon dioxide

This work maps the thermodynamics of electrochemically generated C-nucleophiles for reactive capture of CO(2). We identify a linear relationship between the pK(a), the reduction potential of a protonated nucleophile (E(red)), and the nucleophile’s free energy of CO(2) binding ([Formula: see text])....

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Detalles Bibliográficos
Autores principales: Petersen, Haley A., Alherz, Abdulaziz W., Stinson, Taylor A., Huntzinger, Chloe G., Musgrave, Charles B., Luca, Oana R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8927916/
https://www.ncbi.nlm.nih.gov/pubmed/35310940
http://dx.doi.org/10.1016/j.isci.2022.103997

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