Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

[Image: see text] A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques—reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes—is repor...

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Autores principales: Aydogan, Cansu, Aykac, F. Simal, Yilmaz, Gorkem, Chew, Ye Qiu, Goto, Atsushi, Yagci, Yusuf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928464/
https://www.ncbi.nlm.nih.gov/pubmed/35575368
http://dx.doi.org/10.1021/acsmacrolett.2c00004
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author Aydogan, Cansu
Aykac, F. Simal
Yilmaz, Gorkem
Chew, Ye Qiu
Goto, Atsushi
Yagci, Yusuf
author_facet Aydogan, Cansu
Aykac, F. Simal
Yilmaz, Gorkem
Chew, Ye Qiu
Goto, Atsushi
Yagci, Yusuf
author_sort Aydogan, Cansu
collection PubMed
description [Image: see text] A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques—reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes—is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by (1)H NMR, FT-IR, GPC, and DSC investigations.
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spelling pubmed-89284642022-03-18 Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process Aydogan, Cansu Aykac, F. Simal Yilmaz, Gorkem Chew, Ye Qiu Goto, Atsushi Yagci, Yusuf ACS Macro Lett [Image: see text] A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques—reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes—is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by (1)H NMR, FT-IR, GPC, and DSC investigations. American Chemical Society 2022-02-22 2022-03-15 /pmc/articles/PMC8928464/ /pubmed/35575368 http://dx.doi.org/10.1021/acsmacrolett.2c00004 Text en © 2022 American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Aydogan, Cansu
Aykac, F. Simal
Yilmaz, Gorkem
Chew, Ye Qiu
Goto, Atsushi
Yagci, Yusuf
Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title_full Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title_fullStr Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title_full_unstemmed Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title_short Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
title_sort synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928464/
https://www.ncbi.nlm.nih.gov/pubmed/35575368
http://dx.doi.org/10.1021/acsmacrolett.2c00004
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