Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines

[Image: see text] A metal-free scalable synthesis of functionalized ketenimines from alkyl α-(aryl/heteroaryl)-α-diazoacetates and alkyl isocyanides induced by blue light irradiation has been developed. The reaction proceeds at room temperature without any photocatalyst and provides ketenimines in m...

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Detalles Bibliográficos
Autores principales: Sakharov, Pavel A., Novikov, Mikhail S., Nguyen, Tuan K., Kinzhalov, Mikhail A., Khlebnikov, Alexander F., Rostovskii, Nikolai V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928522/
https://www.ncbi.nlm.nih.gov/pubmed/35309460
http://dx.doi.org/10.1021/acsomega.2c00367

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928522/
https://www.ncbi.nlm.nih.gov/pubmed/35309460
http://dx.doi.org/10.1021/acsomega.2c00367

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