Cargando…

Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon

[Image: see text] To clarify the K modified effects over activated carbon (AC) supported Mn–Ce oxide catalysts, several Mn–Ce/AC and xK–Mn–Ce/AC mixed oxide catalysts prepared via an impregnation method supported on AC were investigated for low-temperature selective catalytic reduction (SCR) of NO w...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Zhenghua, Xing, Xiangdong, Wang, Sunxuan, Lv, Ming, Li, Jinke, Li, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928529/
https://www.ncbi.nlm.nih.gov/pubmed/35309461
http://dx.doi.org/10.1021/acsomega.1c07076
_version_ 1784670661563645952
author Shen, Zhenghua
Xing, Xiangdong
Wang, Sunxuan
Lv, Ming
Li, Jinke
Li, Tao
author_facet Shen, Zhenghua
Xing, Xiangdong
Wang, Sunxuan
Lv, Ming
Li, Jinke
Li, Tao
author_sort Shen, Zhenghua
collection PubMed
description [Image: see text] To clarify the K modified effects over activated carbon (AC) supported Mn–Ce oxide catalysts, several Mn–Ce/AC and xK–Mn–Ce/AC mixed oxide catalysts prepared via an impregnation method supported on AC were investigated for low-temperature selective catalytic reduction (SCR) of NO with NH(3) in the simulated sintering flue gas. The Mn–Ce/AC catalyst with a K loading of 8% showed the highest catalytic activity, corresponding to 92.1% NO conversion and 92.5% N(2) selectivity at 225 °C with a space velocity of 12,000 h(–1). Furthermore, the 0.08K–Mn–Ce/AC catalyst exhibited better resistance to SO(2) and H(2)O than Mn–Ce/AC, which could convert 72.3% and 74.1% of NO at the presence of 5% SO(2) and H(2)O, respectively. After K modification, the relative ratios of Mn(4+)/Mn(n+) as well as Ce(3+)/Ce(n+) and surface adsorbed oxygen increased. Additionally, the reduction performance of the catalyst was improved obviously, and both acid strength and quantity of acid sites increased significantly after the K species were introduced in Mn–Ce/AC. Especially, the NO adsorption capacity of the catalyst was enhanced, which remarkably promoted the denitration efficiency and SO(2) resistance. The SCR of NO with NH(3) on K–Mn–Ce/AC catalysts followed the L-H mechanism.
format Online
Article
Text
id pubmed-8928529
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-89285292022-03-18 Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon Shen, Zhenghua Xing, Xiangdong Wang, Sunxuan Lv, Ming Li, Jinke Li, Tao ACS Omega [Image: see text] To clarify the K modified effects over activated carbon (AC) supported Mn–Ce oxide catalysts, several Mn–Ce/AC and xK–Mn–Ce/AC mixed oxide catalysts prepared via an impregnation method supported on AC were investigated for low-temperature selective catalytic reduction (SCR) of NO with NH(3) in the simulated sintering flue gas. The Mn–Ce/AC catalyst with a K loading of 8% showed the highest catalytic activity, corresponding to 92.1% NO conversion and 92.5% N(2) selectivity at 225 °C with a space velocity of 12,000 h(–1). Furthermore, the 0.08K–Mn–Ce/AC catalyst exhibited better resistance to SO(2) and H(2)O than Mn–Ce/AC, which could convert 72.3% and 74.1% of NO at the presence of 5% SO(2) and H(2)O, respectively. After K modification, the relative ratios of Mn(4+)/Mn(n+) as well as Ce(3+)/Ce(n+) and surface adsorbed oxygen increased. Additionally, the reduction performance of the catalyst was improved obviously, and both acid strength and quantity of acid sites increased significantly after the K species were introduced in Mn–Ce/AC. Especially, the NO adsorption capacity of the catalyst was enhanced, which remarkably promoted the denitration efficiency and SO(2) resistance. The SCR of NO with NH(3) on K–Mn–Ce/AC catalysts followed the L-H mechanism. American Chemical Society 2022-03-04 /pmc/articles/PMC8928529/ /pubmed/35309461 http://dx.doi.org/10.1021/acsomega.1c07076 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Shen, Zhenghua
Xing, Xiangdong
Wang, Sunxuan
Lv, Ming
Li, Jinke
Li, Tao
Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title_full Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title_fullStr Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title_full_unstemmed Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title_short Effect of K-Modified Blue Coke-Based Activated Carbon on Low Temperature Catalytic Performance of Supported Mn–Ce/Activated Carbon
title_sort effect of k-modified blue coke-based activated carbon on low temperature catalytic performance of supported mn–ce/activated carbon
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928529/
https://www.ncbi.nlm.nih.gov/pubmed/35309461
http://dx.doi.org/10.1021/acsomega.1c07076
work_keys_str_mv AT shenzhenghua effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon
AT xingxiangdong effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon
AT wangsunxuan effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon
AT lvming effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon
AT lijinke effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon
AT litao effectofkmodifiedbluecokebasedactivatedcarbononlowtemperaturecatalyticperformanceofsupportedmnceactivatedcarbon