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Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method

[Image: see text] Our previous work had demonstrated that UV/NaClO(2) was the best advanced oxidation method in terms of nitric oxide (NO) removal, but we have not studied the impact of the fly ash on NO removal under such conditions. For this, this paper selected six kinds of fly ashes and studied...

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Autores principales: Zhang, Zili, Lin, Yao, Meng, Jianwei, Wang, Lei, Yao, Qin, Chen, Xiaohan, Dai, Guodong, Zhao, Yi, Hao, Runlong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928542/
https://www.ncbi.nlm.nih.gov/pubmed/35309458
http://dx.doi.org/10.1021/acsomega.1c06930
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author Zhang, Zili
Lin, Yao
Meng, Jianwei
Wang, Lei
Yao, Qin
Chen, Xiaohan
Dai, Guodong
Zhao, Yi
Hao, Runlong
author_facet Zhang, Zili
Lin, Yao
Meng, Jianwei
Wang, Lei
Yao, Qin
Chen, Xiaohan
Dai, Guodong
Zhao, Yi
Hao, Runlong
author_sort Zhang, Zili
collection PubMed
description [Image: see text] Our previous work had demonstrated that UV/NaClO(2) was the best advanced oxidation method in terms of nitric oxide (NO) removal, but we have not studied the impact of the fly ash on NO removal under such conditions. For this, this paper selected six kinds of fly ashes and studied their effects on NO removal. The micromorphology, elemental composition, and the elemental oxidation states of these six fly ashes were characterized by scanning electron microscopy-energy-dispersive X-ray spectra, X-ray photoelectron spectroscopy, and inductively coupled plasma methods. The main inorganic components in the six fly ashes are metal oxides (Fe(2)O(3)/Fe(3)O(4), SiO(2), Al(2)O(3), ZnO, MgO, and TiO(2)), carbonates (Na(2)CO(3) and CaCO(3)), and chlorides (NaCl, KCl, and MgCl(2)). The experimental results suggested that high solubility was the premise condition for the fly ashes exhibiting an inhibitory effect on NO removal. Among all of the metal compounds, Fe(2)O(3)/Fe(3)O(4) exhibited the highest inhibitory contribution rate to the NO removal (22.9–45.7%). The anions of Cl(–) and CO(3)(2–) acted as scavengers for the free radicals which greatly impaired the oxidation of NO. Based on the simulation experimental results and the UV–vis analysis, the order of inhibitory contribution rates of various metal compounds to the NO removal was determined as Fe(2)O(3)/Fe(3)O(4) > TiO(2) ≈ Na(2)CO(3) > Al(2)O(3) ≈ ZnO ≈ MnO(2) > CaCO(3) > NaCl > KCl ≈ SiO(2) ≈ MgCl(2).
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spelling pubmed-89285422022-03-18 Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method Zhang, Zili Lin, Yao Meng, Jianwei Wang, Lei Yao, Qin Chen, Xiaohan Dai, Guodong Zhao, Yi Hao, Runlong ACS Omega [Image: see text] Our previous work had demonstrated that UV/NaClO(2) was the best advanced oxidation method in terms of nitric oxide (NO) removal, but we have not studied the impact of the fly ash on NO removal under such conditions. For this, this paper selected six kinds of fly ashes and studied their effects on NO removal. The micromorphology, elemental composition, and the elemental oxidation states of these six fly ashes were characterized by scanning electron microscopy-energy-dispersive X-ray spectra, X-ray photoelectron spectroscopy, and inductively coupled plasma methods. The main inorganic components in the six fly ashes are metal oxides (Fe(2)O(3)/Fe(3)O(4), SiO(2), Al(2)O(3), ZnO, MgO, and TiO(2)), carbonates (Na(2)CO(3) and CaCO(3)), and chlorides (NaCl, KCl, and MgCl(2)). The experimental results suggested that high solubility was the premise condition for the fly ashes exhibiting an inhibitory effect on NO removal. Among all of the metal compounds, Fe(2)O(3)/Fe(3)O(4) exhibited the highest inhibitory contribution rate to the NO removal (22.9–45.7%). The anions of Cl(–) and CO(3)(2–) acted as scavengers for the free radicals which greatly impaired the oxidation of NO. Based on the simulation experimental results and the UV–vis analysis, the order of inhibitory contribution rates of various metal compounds to the NO removal was determined as Fe(2)O(3)/Fe(3)O(4) > TiO(2) ≈ Na(2)CO(3) > Al(2)O(3) ≈ ZnO ≈ MnO(2) > CaCO(3) > NaCl > KCl ≈ SiO(2) ≈ MgCl(2). American Chemical Society 2022-03-03 /pmc/articles/PMC8928542/ /pubmed/35309458 http://dx.doi.org/10.1021/acsomega.1c06930 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Zhang, Zili
Lin, Yao
Meng, Jianwei
Wang, Lei
Yao, Qin
Chen, Xiaohan
Dai, Guodong
Zhao, Yi
Hao, Runlong
Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title_full Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title_fullStr Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title_full_unstemmed Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title_short Reaction Behavior and Influencing Mechanisms of Different Fly Ashes on the NO Removal by Using the Ultraviolet Irradiating Chlorite Method
title_sort reaction behavior and influencing mechanisms of different fly ashes on the no removal by using the ultraviolet irradiating chlorite method
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8928542/
https://www.ncbi.nlm.nih.gov/pubmed/35309458
http://dx.doi.org/10.1021/acsomega.1c06930
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