Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts

[Image: see text] Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalys...

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Autores principales: Caniparoli, Ulysse, Escofet, Imma, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8938926/
https://www.ncbi.nlm.nih.gov/pubmed/35356706
http://dx.doi.org/10.1021/acscatal.1c05827
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author Caniparoli, Ulysse
Escofet, Imma
Echavarren, Antonio M.
author_facet Caniparoli, Ulysse
Escofet, Imma
Echavarren, Antonio M.
author_sort Caniparoli, Ulysse
collection PubMed
description [Image: see text] Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions.
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spelling pubmed-89389262022-03-28 Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts Caniparoli, Ulysse Escofet, Imma Echavarren, Antonio M. ACS Catal [Image: see text] Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions. American Chemical Society 2022-02-25 2022-03-18 /pmc/articles/PMC8938926/ /pubmed/35356706 http://dx.doi.org/10.1021/acscatal.1c05827 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Caniparoli, Ulysse
Escofet, Imma
Echavarren, Antonio M.
Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title_full Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title_fullStr Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title_full_unstemmed Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title_short Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
title_sort planar chiral 1,3-disubstituted ferrocenyl phosphine gold(i) catalysts
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8938926/
https://www.ncbi.nlm.nih.gov/pubmed/35356706
http://dx.doi.org/10.1021/acscatal.1c05827
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AT escofetimma planarchiral13disubstitutedferrocenylphosphinegoldicatalysts
AT echavarrenantoniom planarchiral13disubstitutedferrocenylphosphinegoldicatalysts

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