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The Role of the Fused Ring in Bicyclic Triazolium Organocatalysts: Kinetic, X-ray, and DFT Insights

[Image: see text] Bicyclic triazolium scaffolds are widely employed in N-heterocyclic carbene (NHC) organocatalysis. While the incorporation of a fused ring was initially for synthetic utility in accessing chiral, modular triazolyl scaffolds, recent results highlight the potential for impact upon re...

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Detalles Bibliográficos
Autores principales: Zhu, Jiayun, Moreno, Inmaculada, Quinn, Peter, Yufit, Dmitry S., Song, Lijuan, Young, Claire M., Duan, Zhuan, Tyler, Andrew R., Waddell, Paul G., Hall, Michael J., Probert, Michael R., Smith, Andrew D., O’Donoghue, AnnMarie C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8938951/
https://www.ncbi.nlm.nih.gov/pubmed/35230109
http://dx.doi.org/10.1021/acs.joc.1c03073