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Reversible Redox Chemistry of Anionic Imidazole-2-thione-Fused 1,4-Dihydro-1,4-diphosphinines

[Image: see text] Anionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[2a–2c]. Reaction of solutions of these monoanions with iodomethane led to P-methylated compounds 3a–3c. An oxidation/reduction cycle was examined, starting...

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Detalles Bibliográficos
Autores principales:	Ramachandran, Mridhul R. K., Schnakenburg, Gregor, Majumdar, Moumita, Kelemen, Zsolt, Gál, Dalma, Nyulászi, Laszlo, Boeré, René T., Streubel, Rainer K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8941515/ https://www.ncbi.nlm.nih.gov/pubmed/35258281 http://dx.doi.org/10.1021/acs.inorgchem.1c03620

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