Synthesis of a biomimetic zwitterionic pentapolymer to fabricate high-performance PVDF membranes for efficient separation of oil-in-water nano-emulsions

Oily wastewater from industries has an adverse impact on the environment, human and aquatic life. Poly(vinylidene fluoride) (PVDF) membrane modified with a zwitterionic/hydrophobic pentapolymer (PP) with controlled pore size has been utilized to separate oil from water from their nano-emulsions. The PP has been synthesized in 91% yield via pentapolymerization of four different diallylamine salts [(CH(2)=CHCH(2))(2)NH(+)(CH(2))(x) A(−)], bearing CO(2)(−), PO(3)H(−), SO(3)(−), (CH(2))(12)NH(2) pendants, and SO(2) in a respective mol ratio of 25:36:25:14:100. Incorporating PP into PVDF has shown a substantially reduced membrane hydrophobicity; the contact angle decreased from 92.5° to 47.4°. The PP-PVDF membranes have demonstrated an excellent capability to deal with the high concentrations of nano-emulsions with a separation efficiency of greater than 97.5%. The flux recovery ratio (FRR) of PP-5 incorporated PVDF membrane was about 82%, which was substantially higher than the pristine PVDF.