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Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

We report the selective electrochemical biphasic capture of the uranyl cation (UO(2)(2+)) from mixed-metal alkali (Cs(+)), lanthanide (Nd(3+), Sm(3+)), and actinide (Th(4+), UO(2)(2+)) aqueous solutions to an organic, 1,2-dichloroethane (DCE), phase using the ortho-substituted nido-carborane anion,...

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Detalles Bibliográficos
Autores principales: Keener, Megan, Mattejat, Maxwell, Zheng, Shao-Liang, Wu, Guang, Hayton, Trevor W., Ménard, Gabriel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8943888/
https://www.ncbi.nlm.nih.gov/pubmed/35432881
http://dx.doi.org/10.1039/d1sc07070c