Disilanes with Pentacoordinate Si Atoms by Carbon Dioxide Insertion into Aminodisilanes: Syntheses, Molecular Structures, and Dynamic Behavior

[Image: see text] The insertion of carbon dioxide into the Si–N bonds of aminodisilanes ((RR′N)(n)Me(3–n)Si)(2) affords carbamoyloxydisilanes ((RR′NC(O)O)(n)Me(3–n)Si)(2). Some of the obtained insertion products feature pentacoordinate silicon atoms in the solid state and in solution, with two carba...

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Detalles Bibliográficos
Autores principales: Ryll, Christopher, Kraushaar, Konstantin, Wagler, Jörg, Brendler, Erica, Kroke, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8945131/
https://www.ncbi.nlm.nih.gov/pubmed/35350308
http://dx.doi.org/10.1021/acsomega.1c06868

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