Anaerobic Reactor Filling for Phosphorus Removal by Metal Dissolution Method

A commonly indicated drawback of anaerobic wastewater treatment is the low effectiveness of phosphorus removal. One possibility to eliminate this disadvantage is the implementation of active fillings that contain admixtures of metals, minerals, or other elements contributing to wastewater treatment intensification. The aim of the research was to present an active filling produced via microcellular extrusion technology, and to determine its properties and performance in anaerobic wastewater treatment. The influence of copper and iron admixtures on the properties of the obtained porous extrudate in terms of its functional properties was also examined. The Barus effect increased with the highest content of the blowing agent in the material from 110 ± 12 to 134 ± 14. The addition of metal powders caused an increase in the extrudate density. The modification of PVC resulted in the highest porosity, amounting to 47.0% ± 3.2%, and caused the tensile strength to decrease by about 50%. The determined values ranged from 211.8 ± 18.3 MPa to 97.1 ± 10.0 MPa. The use of the filling in anaerobic rectors promoted COD removal, intensified biogas production, and eliminated phosphorus with an efficiency of 64.4% to 90.7%, depending on the type of wastewater and applied technological parameters.