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Metal–Organic-Framework-Derived Ball-Flower-like Porous Co(3)O(4)/Fe(2)O(3) Heterostructure with Enhanced Visible-Light-Driven Photocatalytic Activity

A porous ball-flower-like Co(3)O(4)/Fe(2)O(3) heterostructural photocatalyst was synthesized via a facile metal–organic-framework-templated method, and showed an excellent degradation performance in the model molecule rhodamine B under visible light irradiation. This enhanced photocatalytic activity...

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Detalles Bibliográficos
Autores principales: Cao, Qi, Li, Qingqing, Pi, Zhichao, Zhang, Jing, Sun, Li-Wei, Xu, Junzhou, Cao, Yunyi, Cheng, Junye, Bian, Ye
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8951189/
https://www.ncbi.nlm.nih.gov/pubmed/35335718
http://dx.doi.org/10.3390/nano12060904
Descripción
Sumario:A porous ball-flower-like Co(3)O(4)/Fe(2)O(3) heterostructural photocatalyst was synthesized via a facile metal–organic-framework-templated method, and showed an excellent degradation performance in the model molecule rhodamine B under visible light irradiation. This enhanced photocatalytic activity can be attributed to abundant photo-generated holes and hydroxyl radicals, and the combined effects involving a porous structure, strong visible-light absorption, and improved interfacial charge separation. It is notable that the ecotoxicity of the treated reaction solution was also evaluated, confirming that an as-synthesized Co(3)O(4)/Fe(2)O(3) catalyst could afford the sunlight-driven long-term recyclable degradation of dye-contaminated wastewater into non-toxic and colorless wastewater.