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Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries

Rechargeable lithium-ion batteries have drawn extensive attention owing to increasing demands in applications from portable electronic devices to energy storage systems. In situ polymerization is considered one of the most promising approaches for enabling interfacial issues and improving compatibil...

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Autores principales: Zhang, Wei, Yoon, Sujin, Jin, Lei, Lim, Hyunmin, Jeon, Minhyuk, Jang, Hohyoun, Ahmed, Faiz, Kim, Whangi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8955661/
https://www.ncbi.nlm.nih.gov/pubmed/35323805
http://dx.doi.org/10.3390/membranes12030330
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author Zhang, Wei
Yoon, Sujin
Jin, Lei
Lim, Hyunmin
Jeon, Minhyuk
Jang, Hohyoun
Ahmed, Faiz
Kim, Whangi
author_facet Zhang, Wei
Yoon, Sujin
Jin, Lei
Lim, Hyunmin
Jeon, Minhyuk
Jang, Hohyoun
Ahmed, Faiz
Kim, Whangi
author_sort Zhang, Wei
collection PubMed
description Rechargeable lithium-ion batteries have drawn extensive attention owing to increasing demands in applications from portable electronic devices to energy storage systems. In situ polymerization is considered one of the most promising approaches for enabling interfacial issues and improving compatibility between electrolytes and electrodes in batteries. Herein, we observed in situ thermally induced electrolytes based on an oxetane group with LiFSI as an initiator, and investigated structural characteristics, physicochemical properties, contacting interface, and electrochemical performances of as-prepared SPEs with a variety of technologies, such as FTIR, (1)H-NMR, FE-SEM, EIS, LSV, and chronoamperometry. The as-prepared SPEs exhibited good thermal stability (stable up to 210 °C), lower activation energy, and high ionic conductivity (>0.1 mS/cm) at 30 °C. Specifically, SPE-2.5 displayed a comparable ionic conductivity (1.3 mS/cm at 80 °C), better interfacial compatibility, and a high Li-ion transference number. The SPE-2.5 electrolyte had comparable coulombic efficiency with a half-cell configuration at 0.1 C for 50 cycles. Obtained results could provide the possibility of high ionic conductivity and good compatibility through in situ polymerization for the development of Li-ion batteries.
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spelling pubmed-89556612022-03-26 Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries Zhang, Wei Yoon, Sujin Jin, Lei Lim, Hyunmin Jeon, Minhyuk Jang, Hohyoun Ahmed, Faiz Kim, Whangi Membranes (Basel) Article Rechargeable lithium-ion batteries have drawn extensive attention owing to increasing demands in applications from portable electronic devices to energy storage systems. In situ polymerization is considered one of the most promising approaches for enabling interfacial issues and improving compatibility between electrolytes and electrodes in batteries. Herein, we observed in situ thermally induced electrolytes based on an oxetane group with LiFSI as an initiator, and investigated structural characteristics, physicochemical properties, contacting interface, and electrochemical performances of as-prepared SPEs with a variety of technologies, such as FTIR, (1)H-NMR, FE-SEM, EIS, LSV, and chronoamperometry. The as-prepared SPEs exhibited good thermal stability (stable up to 210 °C), lower activation energy, and high ionic conductivity (>0.1 mS/cm) at 30 °C. Specifically, SPE-2.5 displayed a comparable ionic conductivity (1.3 mS/cm at 80 °C), better interfacial compatibility, and a high Li-ion transference number. The SPE-2.5 electrolyte had comparable coulombic efficiency with a half-cell configuration at 0.1 C for 50 cycles. Obtained results could provide the possibility of high ionic conductivity and good compatibility through in situ polymerization for the development of Li-ion batteries. MDPI 2022-03-16 /pmc/articles/PMC8955661/ /pubmed/35323805 http://dx.doi.org/10.3390/membranes12030330 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Wei
Yoon, Sujin
Jin, Lei
Lim, Hyunmin
Jeon, Minhyuk
Jang, Hohyoun
Ahmed, Faiz
Kim, Whangi
Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title_full Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title_fullStr Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title_full_unstemmed Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title_short Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries
title_sort lithium salt catalyzed ring-opening polymerized solid-state electrolyte with comparable ionic conductivity and better interface compatibility for li-ion batteries
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8955661/
https://www.ncbi.nlm.nih.gov/pubmed/35323805
http://dx.doi.org/10.3390/membranes12030330
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