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Hydrolysis of the Borohydride Anion BH(4)(−): A (11)B NMR Study Showing the Formation of Short-Living Reaction Intermediates including BH(3)OH(−)

In hydrolysis and electro-oxidation of the borohydride anion BH(4)(−), key reactions in the field of energy, one critical short-living intermediate is BH(3)OH(−). When water was used as both solvent and reactant, only BH(3)OH(−) is detected by (11)B NMR. By moving away from such conditions and using...

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Detalles Bibliográficos
Autores principales: Petit, Eddy, Salles, Fabrice, Alligier, Damien, Demirci, Umit B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8955758/
https://www.ncbi.nlm.nih.gov/pubmed/35335336
http://dx.doi.org/10.3390/molecules27061975