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Exact closure and solution for spatial correlations in single-file diffusion

In single-file transport particles diffuse in narrow channels while not overtaking each other. it is a fundamental model for the tracer subdiffusion observed in confined systems, such as zeolites or carbon nanotubes. This anomalous behavior originates from strong bath-tracer correlations in one dime...

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Detalles Bibliográficos
Autores principales: Grabsch, Aurélien, Poncet, Alexis, Rizkallah, Pierre, Illien, Pierre, Bénichou, Olivier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8956262/
https://www.ncbi.nlm.nih.gov/pubmed/35333581
http://dx.doi.org/10.1126/sciadv.abm5043
Descripción
Sumario:In single-file transport particles diffuse in narrow channels while not overtaking each other. it is a fundamental model for the tracer subdiffusion observed in confined systems, such as zeolites or carbon nanotubes. This anomalous behavior originates from strong bath-tracer correlations in one dimension. Despite extensive effort, these remained elusive, because they involve an infinite hierarchy of equations. For the symmetric exclusion process, a paradigmatic model of single-file diffusion, we break the hierarchy to unveil and solve a closed exact equation satisfied by these correlations. Beyond quantifying the correlations, the role of this key equation as a tool for interacting particle systems is further demonstrated by its application to out-of-equilibrium situations, other observables, and other representative single-file systems.