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Unusual (2R,6R)-bicyclo[3.1.1]heptane ring construction in fungal α-trans-bergamotene biosynthesis

Bergamotenes are bicyclo[3.1.1]heptane sesquiterpenes found abundantly in plants and fungi. Known bergamotene derivatives all possess (2S,6S)-bergamotene backbone. In this study, two (+)-α-trans-bergamotene derivatives (1 and 2) with unusual (2R,6R) configuration were isolated and elucidated from ma...

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Detalles Bibliográficos
Autores principales: Wen, Yan-Hua, Chen, Tian-Jiao, Jiang, Long-Yu, Li, Li, Guo, Mengbo, Peng, Yu, Chen, Jing-Jing, Pei, Fei, Yang, Jin-Ling, Wang, Rui-Shan, Gong, Ting, Zhu, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8956814/
https://www.ncbi.nlm.nih.gov/pubmed/35345459
http://dx.doi.org/10.1016/j.isci.2022.104030

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