Does Steric Hindrance Actually Govern the Competition between Bimolecular Substitution and Elimination Reactions?

[Image: see text] Bimolecular nucleophilic substitution (S(N)2) and elimination (E2) reactions are prototypical examples of competing reaction mechanisms, with fundamental implications in modern chemical synthesis. Steric hindrance (SH) is often considered to be one of the dominant factors determini...

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Detalles Bibliográficos
Autores principales: Gallegos, Miguel, Costales, Aurora, Martín Pendás, Ángel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8958592/
https://www.ncbi.nlm.nih.gov/pubmed/35290051
http://dx.doi.org/10.1021/acs.jpca.2c00415

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8958592/
https://www.ncbi.nlm.nih.gov/pubmed/35290051
http://dx.doi.org/10.1021/acs.jpca.2c00415

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