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Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water

A highly efficient and mild palladium-catalyzed hydroboration of unactivated internal alkynes in water is described. Both aryl- and alkyl-substituted alkynes proceeded smoothly within the reaction time to afford the desired vinylboronates in moderate to high yields. Bis (pinacolato) diboron was used...

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Detalles Bibliográficos
Autores principales: Yang, Ming, Yu, Yunzi, Ma, Wenxia, Feng, Yuqin, Zhang, Gang, Wu, Yaqi, Zhou, Fanyu, Yang, Yongsheng, Liu, Dezheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8961796/
https://www.ncbi.nlm.nih.gov/pubmed/35424934
http://dx.doi.org/10.1039/d1ra09136k