Diastereomeric dinickel(ii) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane

Diastereomeric dinickel(ii) complexes with bis-octaazamacrocyclic 15-membered ligands [Ni(L(1–3)–L(1–3))Ni] (4–6) have been prepared by oxidative dehydrogenation of nickel(ii) complexes NiL(1–3) (1–3) derived from 1,2- and 1,3-diketones and S-methylisothiocarbohydrazide. The compounds were character...

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Detalles Bibliográficos
Autores principales: Dobrov, Anatolie, Darvasiová, Denisa, Zalibera, Michal, Bučinský, Lukáš, Jelemenská, Ingrid, Rapta, Peter, Shova, Sergiu, Dumitrescu, Dan G., Andrade, Marta A., Martins, Luísa M. D. R. S., Pombeiro, Armando J. L., Arion, Vladimir B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8962992/
https://www.ncbi.nlm.nih.gov/pubmed/35266945
http://dx.doi.org/10.1039/d2dt00154c

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