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Determining the inherent selectivity for carbon radical hydroxylation versus halogenation with high-spin oxoiron(iv)–halide complexes: a concerted rebound step
A synthetic iron model can process both halogenation and hydroxylation with vague selectivity, which is different from halogenase even though these structures are used for the simulation of halogenase. The key factor of the synthetic oxo-iron model mediated hydroxylation or the halogenation is still...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8963258/ https://www.ncbi.nlm.nih.gov/pubmed/35424943 http://dx.doi.org/10.1039/d2ra01384c |