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Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in su...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965395/ https://www.ncbi.nlm.nih.gov/pubmed/35360352 http://dx.doi.org/10.1098/rsos.211874 |
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author | Yamashita, Aichi Shukunami, Yuta Mizuguchi, Yoshikazu |
author_facet | Yamashita, Aichi Shukunami, Yuta Mizuguchi, Yoshikazu |
author_sort | Yamashita, Aichi |
collection | PubMed |
description | REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in superconductivity application. To accelerate application researches on RE123-based devices, further improvements of J(c) characteristics have been desired. In this study, we investigated the effects of high-entropy alloying at the RE site on the superconducting properties, through the measurements of local (intra-grain) J(c) ([Formula: see text]) by a remanent magnetization method. We found that [Formula: see text] shows a trend to be improved when four or five RE elements are mixed at the RE site, which results in high configurational entropy of mixing (ΔS(mix)). All samples exhibited an order of few MA cm(−2) which is a criterion for practical application and the highest [Formula: see text] resulted in a value of around 7.0 MA cm(−2) at T = 2.0 K. Because high-entropy alloying can improve [Formula: see text] of RE123 superconductors, our entropy-engineering strategy introduced here would be useful for the development of RE123 superconducting materials available under high magnetic fields. |
format | Online Article Text |
id | pubmed-8965395 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-89653952022-03-30 Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing Yamashita, Aichi Shukunami, Yuta Mizuguchi, Yoshikazu R Soc Open Sci Chemistry REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in superconductivity application. To accelerate application researches on RE123-based devices, further improvements of J(c) characteristics have been desired. In this study, we investigated the effects of high-entropy alloying at the RE site on the superconducting properties, through the measurements of local (intra-grain) J(c) ([Formula: see text]) by a remanent magnetization method. We found that [Formula: see text] shows a trend to be improved when four or five RE elements are mixed at the RE site, which results in high configurational entropy of mixing (ΔS(mix)). All samples exhibited an order of few MA cm(−2) which is a criterion for practical application and the highest [Formula: see text] resulted in a value of around 7.0 MA cm(−2) at T = 2.0 K. Because high-entropy alloying can improve [Formula: see text] of RE123 superconductors, our entropy-engineering strategy introduced here would be useful for the development of RE123 superconducting materials available under high magnetic fields. The Royal Society 2022-03-30 /pmc/articles/PMC8965395/ /pubmed/35360352 http://dx.doi.org/10.1098/rsos.211874 Text en © 2022 The Authors. https://creativecommons.org/licenses/by/4.0/Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, provided the original author and source are credited. |
spellingShingle | Chemistry Yamashita, Aichi Shukunami, Yuta Mizuguchi, Yoshikazu Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title | Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title_full | Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title_fullStr | Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title_full_unstemmed | Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title_short | Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing |
title_sort | improvement of critical current density of reba(2)cu(3)o(7-δ) by increase in configurational entropy of mixing |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965395/ https://www.ncbi.nlm.nih.gov/pubmed/35360352 http://dx.doi.org/10.1098/rsos.211874 |
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