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Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing

REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in su...

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Detalles Bibliográficos
Autores principales: Yamashita, Aichi, Shukunami, Yuta, Mizuguchi, Yoshikazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965395/
https://www.ncbi.nlm.nih.gov/pubmed/35360352
http://dx.doi.org/10.1098/rsos.211874
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author Yamashita, Aichi
Shukunami, Yuta
Mizuguchi, Yoshikazu
author_facet Yamashita, Aichi
Shukunami, Yuta
Mizuguchi, Yoshikazu
author_sort Yamashita, Aichi
collection PubMed
description REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in superconductivity application. To accelerate application researches on RE123-based devices, further improvements of J(c) characteristics have been desired. In this study, we investigated the effects of high-entropy alloying at the RE site on the superconducting properties, through the measurements of local (intra-grain) J(c) ([Formula: see text]) by a remanent magnetization method. We found that [Formula: see text] shows a trend to be improved when four or five RE elements are mixed at the RE site, which results in high configurational entropy of mixing (ΔS(mix)). All samples exhibited an order of few MA cm(−2) which is a criterion for practical application and the highest [Formula: see text] resulted in a value of around 7.0 MA cm(−2) at T = 2.0 K. Because high-entropy alloying can improve [Formula: see text] of RE123 superconductors, our entropy-engineering strategy introduced here would be useful for the development of RE123 superconducting materials available under high magnetic fields.
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spelling pubmed-89653952022-03-30 Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing Yamashita, Aichi Shukunami, Yuta Mizuguchi, Yoshikazu R Soc Open Sci Chemistry REBa(2)Cu(3)O(7-)(δ) (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (T(c)) exceeding 90 K. Because of its high-T(c) and large critical current density (J(c)) under magnetic fields, RE123 superconductors have been expected to play a key role in superconductivity application. To accelerate application researches on RE123-based devices, further improvements of J(c) characteristics have been desired. In this study, we investigated the effects of high-entropy alloying at the RE site on the superconducting properties, through the measurements of local (intra-grain) J(c) ([Formula: see text]) by a remanent magnetization method. We found that [Formula: see text] shows a trend to be improved when four or five RE elements are mixed at the RE site, which results in high configurational entropy of mixing (ΔS(mix)). All samples exhibited an order of few MA cm(−2) which is a criterion for practical application and the highest [Formula: see text] resulted in a value of around 7.0 MA cm(−2) at T = 2.0 K. Because high-entropy alloying can improve [Formula: see text] of RE123 superconductors, our entropy-engineering strategy introduced here would be useful for the development of RE123 superconducting materials available under high magnetic fields. The Royal Society 2022-03-30 /pmc/articles/PMC8965395/ /pubmed/35360352 http://dx.doi.org/10.1098/rsos.211874 Text en © 2022 The Authors. https://creativecommons.org/licenses/by/4.0/Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Yamashita, Aichi
Shukunami, Yuta
Mizuguchi, Yoshikazu
Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title_full Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title_fullStr Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title_full_unstemmed Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title_short Improvement of critical current density of REBa(2)Cu(3)O(7-δ) by increase in configurational entropy of mixing
title_sort improvement of critical current density of reba(2)cu(3)o(7-δ) by increase in configurational entropy of mixing
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965395/
https://www.ncbi.nlm.nih.gov/pubmed/35360352
http://dx.doi.org/10.1098/rsos.211874
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