Cargando…

Solvent-mediated outer-sphere CO(2) electro-reduction mechanism over the Ag111 surface

The electrocatalytic CO(2) reduction reaction (CO(2)RR) is one of the key technologies of the clean energy economy. Molecular-level understanding of the CO(2)RR process is instrumental for the better design of electrodes operable at low overpotentials with high current density. The catalytic mechani...

Descripción completa

Detalles Bibliográficos
Autores principales:	Sinha, Vivek, Khramenkova, Elena, Pidko, Evgeny A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966634/ https://www.ncbi.nlm.nih.gov/pubmed/35432905 http://dx.doi.org/10.1039/d1sc07119j

Ejemplares similares

Global optimization of extraframework ensembles in zeolites: structural analysis of extraframework aluminum species in MOR and MFI zeolites
por: Khramenkova, Elena V., et al.
Publicado: (2022)

Solvent-Assisted Ketone Reduction by a Homogeneous Mn Catalyst
por: Krieger, Annika M., et al.
Publicado: (2022)

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin
por: Pankhurst, James R., et al.
Publicado: (2017)

Correction: Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin
por: Pankhurst, James R., et al.
Publicado: (2017)

Ru(III)(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism
por: Chatterjee, Debabrata, et al.
Publicado: (2021)

Engineering lanmodulin's selectivity for actinides over lanthanides by controlling solvent coordination and second-sphere interactions
por: Mattocks, Joseph A., et al.
Publicado: (2022)

ChemSpaX: exploration of chemical space by automated functionalization of molecular scaffold
por: Kalikadien, Adarsh V., et al.
Publicado: (2022)

Contributions to cytochrome c inner- and outer-sphere reorganization energy
por: Chattopadhyay, Samir, et al.
Publicado: (2021)

Hydrogen bond guided synthesis of close-packed one-dimensional graphdiyne on the Ag(111) surface
por: Chen, Zhi, et al.
Publicado: (2019)

High Stability of Methanol to Aromatic Conversion over Bimetallic Ca,Ga-Modified ZSM-5
por: Liu, Chuncheng, et al.
Publicado: (2022)

Outer-sphere effects on ligand-field excited-state dynamics: solvent dependence of high-spin to low-spin conversion in [Fe(bpy)(3)](2+)
por: Miller, Jennifer N., et al.
Publicado: (2020)

Unraveling the Nature of Extraframework Catalytic Ensembles in Zeolites: Flexibility and Dynamics of the Copper-Oxo Trimers in Mordenite
por: Khramenkova, Elena V., et al.
Publicado: (2021)

Chirality variation from self-assembly on Ullmann coupling for the DBCh adsorbate on Au(111) and Ag(111)
por: Wang, Hongbing, et al.
Publicado: (2023)

PdAg/Ag(111) Surface Alloys: A Highly Efficient Catalyst of Oxygen Reduction Reaction
por: Hua, Minghao, et al.
Publicado: (2022)

Crystal phase engineering of silicene by Sn-modified Ag(111)
por: Achilli, Simona, et al.
Publicado: (2023)

An Electron‐Rich Cyclic (Alkyl)(Amino)Carbene on Au(111), Ag(111), and Cu(111) Surfaces
por: Bakker, Anne, et al.
Publicado: (2020)

Depletion sphere: Explaining the number of Ag islands on Au nanoparticles
por: Feng, Yuhua, et al.
Publicado: (2017)

Snapshots of magnesium-centred diborane heterolysis by an outer sphere S(N)2 process
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2019)

Hyperthermal velocity distributions of recombinatively-desorbing oxygen from Ag(111)
por: Dorst, Arved C., et al.
Publicado: (2023)

On‐Surface Metathesis of an Ionic Liquid on Ag(111)
por: Massicot, Stephen, et al.
Publicado: (2022)

Outer coordination sphere influences on cofactor maturation and substrate oxidation by cytochrome P460
por: Bollmeyer, Melissa M., et al.
Publicado: (2023)

Solvent effects on the kinetics of 4-nitrophenol reduction by NaBH(4) in the presence of Ag and Au nanoparticles
por: Lomonosov, Vladimir, et al.
Publicado: (2022)

How solvent determines the molecular reactive conformation and the selectivity: Solvation spheres and energy
por: Hernández-Lima, Joseelyne, et al.
Publicado: (2022)

Time-dependent changes in the growth of ultrathin ionic liquid films on Ag(111)
por: Lexow, Matthias, et al.
Publicado: (2018)

Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)
por: Karatok, Mustafa, et al.
Publicado: (2020)

First-principles study of Mn(3) adsorbed on Au(111) and Cu(111) surfaces
por: Hernández-Vázquez, E. E., et al.
Publicado: (2021)

Nitrogen-doped porous carbon sphere supported Pt nanoparticles for methanol and ethanol electro-oxidation in alkaline media
por: Zhai, Cuiping, et al.
Publicado: (2018)

Unraveling reaction networks behind the catalytic oxidation of methane with H(2)O(2) over a mixed-metal MIL-53(Al,Fe) MOF catalyst
por: Szécsényi, Ágnes, et al.
Publicado: (2018)

Mechanism of atom economical conversion of alcohols and amines to amides using Fe(ii) pincer catalyst. An outer-sphere metal–ligand pathway or an inner-sphere elimination pathway?
por: Shiekh, Bilal Ahmad, et al.
Publicado: (2019)

Natural Deep Eutectic Solvents Enhanced Electro-Enzymatic Conversion of CO(2) to Methanol
por: Zhang, Zhibo, et al.
Publicado: (2022)

Kinetic and mechanistic analysis of NH(3) decomposition on Ru(0001), Ru(111) and Ir(111) surfaces
por: Lu, Xiuyuan, et al.
Publicado: (2021)

The influence of adsorption geometry on the reduction affinity of nitroaromatics on Au(111)
por: Berg, Iris, et al.
Publicado: (2022)

Secondary-Sphere Effects in Molecular Electrocatalytic CO(2) Reduction
por: Nichols, Asa W., et al.
Publicado: (2019)

Controlling a burn: outer-sphere gating of hydroxylamine oxidation by a distal base in cytochrome P460
por: Smith, Meghan A., et al.
Publicado: (2019)

Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework
por: Zee, David Z., et al.
Publicado: (2020)

Enhanced photocatalytic reduction of CO(2) to CO over BiOBr assisted by phenolic resin-based activated carbon spheres
por: Liu, Kangli, et al.
Publicado: (2019)

Nonintuitive Surface Self-Assembly of Functionalized Molecules on Ag(111)
por: Jeindl, Andreas, et al.
Publicado: (2021)

Structural and electronic properties of graphene nanoflakes on Au(111) and Ag(111)
por: Tesch, Julia, et al.
Publicado: (2016)

Outer-coordination sphere in multi-H(+)/multi-e(–)molecular electrocatalysis
por: Sinha, Soumalya, et al.
Publicado: (2021)

A syn outer-sphere oxidative addition: the reaction mechanism in Pd/Senphos-catalyzed carboboration of 1,3-enynes
por: Wang, Ziyong, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_g9fipu8g5h8jjblpp8c9mt8v8i