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Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides

Cycloaddition reactions of distibene [L(Me(2)N)GaSb](2) (L = HC[C(Me)NDipp](2); Dipp = 2,6-i-Pr(2)C(6)H(3))[double bond, length as m-dash] with a series of organoazides RN(3) (R = Ph, p-CF(3)Ph, 1-adamantyl (ada)) yielded azadistibiranes [L(Me(2)N)GaSb](2)NR (R = Ph 1, p-CF(3)Ph 2, ada 3), whereas M...

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Detalles Bibliográficos
Autores principales: Weinert, Hanns M., Wölper, Christoph, Schulz, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966720/
https://www.ncbi.nlm.nih.gov/pubmed/35432897
http://dx.doi.org/10.1039/d2sc00314g