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Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides
Cycloaddition reactions of distibene [L(Me(2)N)GaSb](2) (L = HC[C(Me)NDipp](2); Dipp = 2,6-i-Pr(2)C(6)H(3))[double bond, length as m-dash] with a series of organoazides RN(3) (R = Ph, p-CF(3)Ph, 1-adamantyl (ada)) yielded azadistibiranes [L(Me(2)N)GaSb](2)NR (R = Ph 1, p-CF(3)Ph 2, ada 3), whereas M...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966720/ https://www.ncbi.nlm.nih.gov/pubmed/35432897 http://dx.doi.org/10.1039/d2sc00314g |