A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media

The covalent assembly between a cobalt diimine-dioxime complex and a fullerenic moiety results in enhanced catalytic properties in terms of overpotential requirement for H(2) evolution. The interaction between the fullerene moiety and PCBM heterojunction further allows for the easy integration of th...

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Autores principales: Sun, Dongyue, Morozan, Adina, Koepf, Matthieu, Artero, Vincent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966733/
https://www.ncbi.nlm.nih.gov/pubmed/35432907
http://dx.doi.org/10.1039/d1sc06335a
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author Sun, Dongyue
Morozan, Adina
Koepf, Matthieu
Artero, Vincent
author_facet Sun, Dongyue
Morozan, Adina
Koepf, Matthieu
Artero, Vincent
author_sort Sun, Dongyue
collection PubMed
description The covalent assembly between a cobalt diimine-dioxime complex and a fullerenic moiety results in enhanced catalytic properties in terms of overpotential requirement for H(2) evolution. The interaction between the fullerene moiety and PCBM heterojunction further allows for the easy integration of the cobalt diimine-dioxime – fullerene catalyst with a poly-3-hexylthiophene (P3HT):[6,6]-phenyl-C(61)-butyric acid methyl ester (PCBM) bulk heterojunction, yielding hybrid photoelectrodes for H(2) evolution from near-neutral aqueous solutions.
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spelling pubmed-89667332022-04-14 A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media Sun, Dongyue Morozan, Adina Koepf, Matthieu Artero, Vincent Chem Sci Chemistry The covalent assembly between a cobalt diimine-dioxime complex and a fullerenic moiety results in enhanced catalytic properties in terms of overpotential requirement for H(2) evolution. The interaction between the fullerene moiety and PCBM heterojunction further allows for the easy integration of the cobalt diimine-dioxime – fullerene catalyst with a poly-3-hexylthiophene (P3HT):[6,6]-phenyl-C(61)-butyric acid methyl ester (PCBM) bulk heterojunction, yielding hybrid photoelectrodes for H(2) evolution from near-neutral aqueous solutions. The Royal Society of Chemistry 2022-03-07 /pmc/articles/PMC8966733/ /pubmed/35432907 http://dx.doi.org/10.1039/d1sc06335a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Sun, Dongyue
Morozan, Adina
Koepf, Matthieu
Artero, Vincent
A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title_full A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title_fullStr A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title_full_unstemmed A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title_short A covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
title_sort covalent cobalt diimine-dioxime – fullerene assembly for photoelectrochemical hydrogen production from near-neutral aqueous media
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966733/
https://www.ncbi.nlm.nih.gov/pubmed/35432907
http://dx.doi.org/10.1039/d1sc06335a
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