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Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators

Due to their great load-bearing capabilities, steel–cement interface structures are commonly employed in construction projects, and power utilities including electric insulators. The service life of the steel–cement interface is always decreasing owing to fracture propagation in the cement helped by...

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Autores principales: Sanyal, Simpy, Chelliah, Ramachandran, Kim, Taeyong, Rabelo, Matheus, Oh, Deog-Hawn, Pham, Duy Phong, Yi, Junsin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8968190/
https://www.ncbi.nlm.nih.gov/pubmed/35424936
http://dx.doi.org/10.1039/d2ra00747a
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author Sanyal, Simpy
Chelliah, Ramachandran
Kim, Taeyong
Rabelo, Matheus
Oh, Deog-Hawn
Pham, Duy Phong
Yi, Junsin
author_facet Sanyal, Simpy
Chelliah, Ramachandran
Kim, Taeyong
Rabelo, Matheus
Oh, Deog-Hawn
Pham, Duy Phong
Yi, Junsin
author_sort Sanyal, Simpy
collection PubMed
description Due to their great load-bearing capabilities, steel–cement interface structures are commonly employed in construction projects, and power utilities including electric insulators. The service life of the steel–cement interface is always decreasing owing to fracture propagation in the cement helped by steel corrosion. In this paper, a noble crack-resistant solution for steel–cement interfaces utilized in hostile outdoor environments is proposed. A Ce-rich, homogeneous, and thick hydrophobic sealing coating (HSC) is developed on the steel–cement interface after 60 minutes of immersion in a 60 000 ppm CeCl(3)·7H(2)O sealing coating solution. The specimens treated with optimized HSC film demonstrate fissure filling, lowest corrosion current (I(corr)) 2.3 × 10(−7) A cm(−2), maximum hardness (109 Hv), oxide-jacking resistance (40 years), hydrophobic characteristics, carbonation resistance, and bacterial corrosion resistance, resulting in a crack-free steel–cement interface. This work will pave the way for a new branch of environmentally acceptable coatings for the construction and power industries.
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spelling pubmed-89681902022-04-13 Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators Sanyal, Simpy Chelliah, Ramachandran Kim, Taeyong Rabelo, Matheus Oh, Deog-Hawn Pham, Duy Phong Yi, Junsin RSC Adv Chemistry Due to their great load-bearing capabilities, steel–cement interface structures are commonly employed in construction projects, and power utilities including electric insulators. The service life of the steel–cement interface is always decreasing owing to fracture propagation in the cement helped by steel corrosion. In this paper, a noble crack-resistant solution for steel–cement interfaces utilized in hostile outdoor environments is proposed. A Ce-rich, homogeneous, and thick hydrophobic sealing coating (HSC) is developed on the steel–cement interface after 60 minutes of immersion in a 60 000 ppm CeCl(3)·7H(2)O sealing coating solution. The specimens treated with optimized HSC film demonstrate fissure filling, lowest corrosion current (I(corr)) 2.3 × 10(−7) A cm(−2), maximum hardness (109 Hv), oxide-jacking resistance (40 years), hydrophobic characteristics, carbonation resistance, and bacterial corrosion resistance, resulting in a crack-free steel–cement interface. This work will pave the way for a new branch of environmentally acceptable coatings for the construction and power industries. The Royal Society of Chemistry 2022-03-31 /pmc/articles/PMC8968190/ /pubmed/35424936 http://dx.doi.org/10.1039/d2ra00747a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Sanyal, Simpy
Chelliah, Ramachandran
Kim, Taeyong
Rabelo, Matheus
Oh, Deog-Hawn
Pham, Duy Phong
Yi, Junsin
Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title_full Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title_fullStr Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title_full_unstemmed Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title_short Crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
title_sort crack resistance of a noble green hydrophobic antimicrobial sealing coating film against environmental corrosion applied on the steel–cement interface for power insulators
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8968190/
https://www.ncbi.nlm.nih.gov/pubmed/35424936
http://dx.doi.org/10.1039/d2ra00747a
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