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Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid
Activated-hydrochar (AHC) derived from sugarcane bagasse was synthesized by hydrothermal carbonization (HTC) using phosphoric acid and sodium hydroxide (NaOH) as activators. The properties of AHC were systematically characterized by elemental analysis, BET, SEM, FTIR, XPS and zeta potential, and app...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979052/ https://www.ncbi.nlm.nih.gov/pubmed/35425169 http://dx.doi.org/10.1039/d1ra08325b |
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author | Zhou, Feng Li, Kai Hang, Fangxue Zhang, Zhiming Chen, Peng Wei, Lin Xie, Caifeng |
author_facet | Zhou, Feng Li, Kai Hang, Fangxue Zhang, Zhiming Chen, Peng Wei, Lin Xie, Caifeng |
author_sort | Zhou, Feng |
collection | PubMed |
description | Activated-hydrochar (AHC) derived from sugarcane bagasse was synthesized by hydrothermal carbonization (HTC) using phosphoric acid and sodium hydroxide (NaOH) as activators. The properties of AHC were systematically characterized by elemental analysis, BET, SEM, FTIR, XPS and zeta potential, and applied to evaluate the adsorption ability of methylene blue (MB) by batch adsorption tests. The MB adsorption isotherm and kinetics of AHC were well described by the Langmuir model and pseudo-second-order kinetic model. Characteristic analysis suggested electrostatic attraction, hydrogen bonding and π–π interactions were the main contributors to MB adsorption. Analysis of mass transfer mechanisms demonstrated the adsorption process towards MB by AHC involved intra-particle diffusion to some extent. Thermodynamic studies indicated MB adsorption was an endothermic, spontaneous process associated with a disorder increase at the solid–liquid interface. The maximum adsorption capacity of AHC for MB was 357.14 mg g(−1) at 303 K. Thus, the combination of HTC in phosphoric acid and NaOH activation offered a facile, green and economical alternative for conversion of sugarcane bagasse into efficient adsorbents used in wastewater treatment. |
format | Online Article Text |
id | pubmed-8979052 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-89790522022-04-13 Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid Zhou, Feng Li, Kai Hang, Fangxue Zhang, Zhiming Chen, Peng Wei, Lin Xie, Caifeng RSC Adv Chemistry Activated-hydrochar (AHC) derived from sugarcane bagasse was synthesized by hydrothermal carbonization (HTC) using phosphoric acid and sodium hydroxide (NaOH) as activators. The properties of AHC were systematically characterized by elemental analysis, BET, SEM, FTIR, XPS and zeta potential, and applied to evaluate the adsorption ability of methylene blue (MB) by batch adsorption tests. The MB adsorption isotherm and kinetics of AHC were well described by the Langmuir model and pseudo-second-order kinetic model. Characteristic analysis suggested electrostatic attraction, hydrogen bonding and π–π interactions were the main contributors to MB adsorption. Analysis of mass transfer mechanisms demonstrated the adsorption process towards MB by AHC involved intra-particle diffusion to some extent. Thermodynamic studies indicated MB adsorption was an endothermic, spontaneous process associated with a disorder increase at the solid–liquid interface. The maximum adsorption capacity of AHC for MB was 357.14 mg g(−1) at 303 K. Thus, the combination of HTC in phosphoric acid and NaOH activation offered a facile, green and economical alternative for conversion of sugarcane bagasse into efficient adsorbents used in wastewater treatment. The Royal Society of Chemistry 2022-01-12 /pmc/articles/PMC8979052/ /pubmed/35425169 http://dx.doi.org/10.1039/d1ra08325b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Zhou, Feng Li, Kai Hang, Fangxue Zhang, Zhiming Chen, Peng Wei, Lin Xie, Caifeng Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title | Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title_full | Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title_fullStr | Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title_full_unstemmed | Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title_short | Efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and NaOH activation of sugarcane bagasse and phosphoric acid |
title_sort | efficient removal of methylene blue by activated hydrochar prepared by hydrothermal carbonization and naoh activation of sugarcane bagasse and phosphoric acid |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979052/ https://www.ncbi.nlm.nih.gov/pubmed/35425169 http://dx.doi.org/10.1039/d1ra08325b |
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