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Hydrodeoxygenation of 2,5-dimethyltetrahydrofuran over bifunctional Pt–Cs(2.5)H(0.5)PW(12)O(40) catalyst in the gas phase: enhancing effect of gold

2,5-Dimethyltetrahydrofuran (DMTHF) is deoxygenated to n-hexane with >99% selectivity at mild conditions (90 °C, 1 bar H(2) pressure, fixed-bed reactor) in the presence of the bifunctional metal-acid catalyst Pt–CsPW comprising Pt and Cs(2.5)H(0.5)PW(12)O(40) (CsPW), an acidic Cs salt of Keggin-t...

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Detalles Bibliográficos
Autores principales: Althikrallah, Hanan, Kozhevnikova, Elena F., Kozhevnikov, Ivan V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979146/
https://www.ncbi.nlm.nih.gov/pubmed/35425256
http://dx.doi.org/10.1039/d1ra09105k