External-stimulus-triggered conformational inversion of mechanically self-locked pseudo[1]catenane and gemini-catenanes based on A1/A2-alkyne–azide-difunctionalized pillar[5]arenes

Herein, we report a methodology for constructing mechanically self-locked molecules (MSMs) through the efficient intramolecular copper(i)-catalyzed alkyne–azide cycloaddition (CuAAC) of self-threaded A1/A2-azido-propargyl-difunctionalized pillar[5]arenes. The obtained monomeric “pseudo[1]catenane” a...

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Detalles Bibliográficos
Autores principales: Al-Azemi, Talal F., Vinodh, Mickey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979204/
https://www.ncbi.nlm.nih.gov/pubmed/35425178
http://dx.doi.org/10.1039/d1ra09043g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979204/
https://www.ncbi.nlm.nih.gov/pubmed/35425178
http://dx.doi.org/10.1039/d1ra09043g

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