Rational and site-selective formation of coordination polymers consisting of d(10) coinage metal ions with thiolate ligands using a metal ion-doped polymer substrate

Here, we report an interfacial approach for fabricating coordination polymers (CPs) consisting of d(10) coinage metal ions with thiolate ligands on a polymer substrate. It was found that CPs were selectively formed on the polymer substrate, resulting in the formation of CP-based thin films. In addit...

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Detalles Bibliográficos
Autores principales: Tsuruoka, Takaaki, Miyashita, Yuri, Yoshino, Ryuki, Fukuoka, Myu, Hirao, Shoya, Takashima, Yohei, Demessence, Aude, Akamatsu, Kensuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979238/
https://www.ncbi.nlm.nih.gov/pubmed/35425361
http://dx.doi.org/10.1039/d2ra00269h
Descripción
Sumario:Here, we report an interfacial approach for fabricating coordination polymers (CPs) consisting of d(10) coinage metal ions with thiolate ligands on a polymer substrate. It was found that CPs were selectively formed on the polymer substrate, resulting in the formation of CP-based thin films. In addition, utilizing a mixed metal ion-doped polymer substrate leads to the formation of mixed-metal CP-based films.

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